Green Chemistry @ MUN

Publications – Kerton

Dr Kerton has a h-index of 35 (based on Scopus Author ID, 6507623214; ResearcherID, B-1444-2012; ORCID 0000-0002-8165-473X  Articles that are not published in an open access journal or via purchased/voucher open access or available on ChemRxiv can be found for free download in post-print form at the MUN Research Repository:

E4. F. M. Kerton, “UN Sustainable Development Goals 14 and 15 – Life below water, Life on land”, RSC Sustainability, 2023, Advance Article,

78. J.L. Vidal, T. Jin, E. Lam, F. Kerton and A. Moores, “Blue is the new green: Valorization of crustacean waste“, Current Research in Green and Sustainable Chemistry, 2022, 100330

77. H. Burke and F. Kerton, “Heavy Metals in Snow Crab (Chionoecetes Opilio) Bio-products”, The Journal of Ocean Techonology, 2022, 17, 103-126,

E3. A. S. Cannon et al, “Women in Green Chemistry and Engineering: Agents of Change Toward the Achievement of a Sustainable Future”, ACS Sustainable Chem. Eng., 2022,

E2. Robin D. Rogers and F. M. Kerton, “Marine-based green chemistry”, Green Chemistry, 2022,

76. J. L. Vidal, B. M. Yavitt, M. D. Wheeler, J. L. Kolwich, L. N. Donovan, C. S. Sit, S. G. Hatzikiriakos, N. K. Jalsa, S. L. MacQuarrie and F. M. Kerton, “Biochar as a Sustainable and Renewable Additive for the Production of Poly(ε-caprolactone) Composites”, Sustainable Chemistry and Pharmacy, 2022, 25, 100586,

E1. P. Anastas et al., “The Power of the United Nations Sustainable Development Goals in Sustainable Chemistry and Engineering Research”, ACS Sustainable Chem. Eng., 2021, 9, 24, 8015–8017

75. J. L. Vidal, O. M. Wyper, S. L. MacQuarrie and F. M. Kerton, “Ring-Closing C-O/C-O Metathesis of Aliphatic Ethers and Esterification of Terpene Alcohols Catalyzed by Functionalized Biochar”, European Journal of Organic Chemistry, 2021, 6052-6056.


74. Q. Zhou, M. Guo, K. Ni and F. M. Kerton, “Construction of supramolecular laccase enzymes and understanding of catalytic dye degradation using multispectral and molecular docking approaches”, Reaction Chemistry & Engineering, 2021, DOI: 10.1039/D1RE00111F

73. K. A. Andrea, M. D. Wheeler and F. M. Kerton, “Borane catalyzed polymerization and depolymerization reactions controlled by Lewis acid strength”, Chemical Communications, 2021, DOI: 10.1039/D1CC02218K

B7. G. Margoutidis, F. M. Kerton “Biomass Processing via Mechanochemical Means” in Biomass Valorization: Sustainable Methods for the Production of Chemicals, Eds. D. Ravelli and C. Samori, Wiley, 2021.

72. J. L. Vidal, S. Gallant, E. Connors, D. Richards, S. MacQuarrie and F. M. Kerton, “Green Solvents for the Liquid-Phase Exfoliation of Biochar”, ACS Sustainable Chemistry and Engineering, 9 (27), 9114–9125, 2021

71. A. Subratti, J. L. Vidal, L. J. Lalgee, F. M. Kerton and N. K. Jalsa*, “Preparation and characterization of biochar derived from the fruit seed of Cedrela odorata L and evaluation of its adsorption capacity with methylene blue”, Sustainable Chemistry and Pharmacy, 21, 100421, 2021

70. Y. Liu and F. M. Kerton, “Mechanistic studies on the formation of 5-hydroxymethylfurfural from the sugars fructose and glucose”, Pure and Applied Chemistry, Special Issue – CHEMRAWN, 93, 463-478, 2021

69. G. Margoutidis, M. Johns and F. M. Kerton, “Dissolution studies of α-chitin fibers in freezing NaOH(aq)”, Cellulose, 28(4), 1885-1891, 2021

68. J. N. Murphy, C. M. Schneider, K. Hawboldt and F. M. Kerton, “Hard to Soft: Biogenic Absorbent Sponge-like Material from Waste Mussel Shells” Matter, 3, 2029-2041, 2020

67. A. I. Elkurtehi and F. M. Kerton “Synthesis of Amino-Phenolate Manganese Complexes and Their Catalytic Activity in Carbon Dioxide Activation and Oxidation Reactions” Can. J. Chem. 2021, 99 (2), 202-208, Invited for a Special Issue dedicated to Professor Bob Morris.

66. K. A. Andrea and F. M. Kerton “Iron-catalyzed reactions of CO2 and epoxides to yield cyclic and polycarbonates”, Polymer Journal, 2021, 53, 29–46 (Special Issue: CO2: Capture of, utilization of, and degradation into)

65. C. M. Laprise, K. A. Hawboldt, F. M. Kerton* and C. M. Kozak* “Synthesis of a Renewable, Waste-Derived Non-Isocyanate Polyurethane From Fish Processing Discards and Cashew Nutshell-Derived Amines”, Macromolecular Rapid Communications, 2021, 42(3), 2000339 (Special Issue: Polymers for a Sustainable Future)

64. H. Plommer, L. Stein, J. N. Murphy, N. Ikpo, N. Mora-Diez and F. M. Kerton “Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure-activity relationships”, Dalton Transactions, 2020, 49, 6884 – 6895 DOI: 10.1039/D0DT00726A


PP1. J. Vidal, S. Gallant, D. Richards, S. MacQuarrie and F. Kerton, “Liquid-Phase Exfoliation of Biochars in Green Solvents and Correlation with Solvent Parameters”, ChemRxiv. Preprint.,


Image by 445693 from Pixabay

63. K. A. Andrea, H. Plommer and F. M. Kerton, “Ring-Opening Polymerizations and Copolymerizations of Epoxides Using Aluminum- and Boron-Centered Catalysts”, European Polymer Journal, 2019, 120, 109202 Special Issue on Ring-Opening Polymerization,


62. K. A. Andrea, and F. M. Kerton*, “Functionalized Polycarbonates via Triphenylborane Catalyzed Polymerization-Hydrosilylation” RSC Advances, 2019, 9, 26542 – 26546, DOI: 10.1039/c9ra05947d  OPEN ACCESS 

TOC Graphic RSCAdv

61. K. A. Andrea, E. D. Butler, T. R. Brown, T. S. Anderson, D. Jagota, C. Rose, E. M. Lee, S. D. Goulding, J. N. Murphy, F. M. Kerton* and C. M. Kozak*, “Iron Complexes for Cyclic and Polycarbonate Formation: Selectivity Control from Ligand Design and Metal-Center Geometry” Inorganic Chemistry, 2019, 58, 11231−11240.


60. J. N. Murphy, C. M. Schneider, L. K. Mailänder, Q. Lepillet, K. Hawboldt and F. M. Kerton, “Wealth from waste: Blue mussels (Mylitus edulis) offer up a sustainable source of natural and synthetic nacre”, Green Chemistry, 2019, 21, 3920 – 3929,

TOC work

59. J. L. Vidal, V. P. Andrea, S. L. MacQuarrie and F. M. Kerton, “Oxidized Biochar as a Simple, Renewable Catalyst for the Production of Cyclic Carbonates from Carbon Dioxide and Epoxides”, ChemCatChem, 2019, 11, 4089–4095, Women of Catalysis Special Issue 👩🏼‍🔬👩🏽‍🔬👩🏾‍🔬👩🏿‍🔬👩🏻‍🔬👩‍🔬 and Hot Topic: Carbon Dioxide

JPG_Graphical abstract (new)

58. H. Plommer, J. N. Murphy, L. N. Dawe and F. M. Kerton, “Morpholine-Stabilized Cationic Aluminum Complexes and Their Reactivity in Ring-Opening Polymerization of ε‑Caprolactone”, Inorganic Chemistry, 2019, 58,  (8), 5253–5264,


57. K. A. Andrea and F. M. Kerton, “Triaryl Borane Catalyzed Formation of Cyclic Organic Carbonates and Polycarbonates”, ACS Catalysis, 2019, 9, 1799 – 1809 DOI: 10.1021/acscatal.8b04282

acs catal toc2 png

56. K. A. Andrea, T. R. Brown, J. N. Murphy, D. Jagota, D. McKearney, C. M. Kozak and F. M. Kerton, “Characterization of oxo-bridged iron amino-bis(phenolate) complexes formed intentionally or in situ: Mechanistic insight into epoxide deoxygenation during the coupling of CO2 and epoxides”, Inorganic Chemistry, 2018, 57, 13494 – 13504,


55. J. Gong, M. J. Katz and F. M. Kerton, “Catalytic Conversion of Glucose to 5-Hydroxymethylfurfural using Zirconium-Containing Metal-Organic Frameworks using Microwave Heating”, RSC Advances, 2018, 8, 31618 – 31627, DOI: 10.1039/C8RA06021E.  OPEN ACCESS 


54. J. N. Murphy, K. Hawboldt and F. M. Kerton, “Enzymatic processing of mussel shells to produce biorenewable calcium carbonate in seawater”, Green Chemistry, 2018, 20, 2913 – 2920, DOI: 10.1039/C8GC01274A


53. G. Margoutidis, V. H. Parsons, C. S. Bottaro, N. Yan and F. M. Kerton, “Mechanochemical amorphization of α-chitin and conversion into oligomers of N-acetyl-D-glucosamine”, ACS Sustainable Chemistry & Engineering, 2018, 6, 1662–1669, DOI:10.1021/acssuschemeng.7b02870.

B6. F.M. Kerton and N. Yan Ed.s (2017)  Fuels, Chemicals and Materials from the Oceans and Aquatic Sources, Wiley Series in Renewable Resources, John Wiley & Sons, Ltd: Chichester, UK. ISBN: 978-1-119-11716-2  (and two chapters therein).

52. Y. Liu, C. Staehler, J. N. Murphy, B. J. Furlong, and F. M. Kerton, “Formation of a renewable amine and an alcohol via transformations of 3-acetamido-5-acetylfuran”, ACS Sustainable Chemistry & Engineering,  2017, 5, 4916–4922, DOI: 10.1021/acssuschemeng.7b00323

51. A. I. Elkurtehi and F. M. Kerton, “Coupling Reactions of Carbon Dioxide with Epoxides Catalyzed by Vanadium Aminophenolate Complexes”, ChemSusChem, 2017, 10, 1249-1254, DOI: 10.1002/cssc.201601548

50. A. I. Elkurtehi, A. G. Walsh, L. N. Dawe, and F. M. Kerton, “Vanadium aminophenolate complexes and their catalytic activity in aerobic and H2O2-mediated oxidation reactions”, Eur. J. Inorg. Chem., 2016, 3123–3130,

49. D. Alhashmialameer,  J. Collins, K. Hattenhauer, and F. M. Kerton, “Iron amino-bis(phenolate) complexes for the formation of organic carbonates from CO2 and oxiranes”, Catal. Sci. Technol., 2016, 5364 – 5373, DOI: 10.1039/C6CY00477FOPEN ACCESS

48. D. Alhashmialameer, N. Ikpo, J. Collins, L. N. Dawe, K. Hattenhauer, and F. M. Kerton, “Ring-opening polymerization of rac-lactide mediated by tetrametallic lithium and sodium diamino-bis(phenolate) complexes”, Dalton Transactions, 2015, 44, 20216 – 20231 DOI:10.1039/c5dt03119b OPEN ACCESS

47. C. F. Petten, H. A. Kalviri and F. M. Kerton, “Halodehydroxylation of alcohols to yield benzylic and alkyl halides in ionic liquids”, Sustainable Chemical Processes (Springer Open), 2015, 3:16, DOI:10.1186/s40508-015-0043-4, Contribution for Special Issue on Green and Sustainable Solvents. OPEN ACCESS

B5. F.M. Kerton (2016) ‘Solvent Systems for Sustainable Chemistry’, in Encyclopedia of Inorganic and Bioinorganic Chemistry, edited by David A. Atwood. John Wiley & Sons, Ltd: Chichester, UK. DOI: 10.1002/9781119951438.eibc2417

46. M. W. Drover et al., “Structural characterization of a tetrametallic diamine-bis(phenolate) complex of lithium and synthesis of a related bismuth complex”, Polyhedron, 2015, 102, 60-68, DOI:10.1016/j.poly.2015.07.071

45. X. Chen, Y. Liu, F. M. Kerton* and N. Yan*, “Conversion of chitin and N-acetyl-D-glucosamine into a N-containing furan derivative in ionic liquids”, RSC Adv., 2015, 5,  20073-20080 DOI: 10.1039/c5ra00382b.

NEWS: F. M. Kerton, Soapbox Section, “Waste not, Want not: Aquaculture by-products put to good use”, Sea Technology Magazine, January 2015

CP1. F. M. Kerton, Y. Liu, J. N. Murphy and K. Hawboldt, “Renewable resouces from the oceans: Adding value to the by-products of the aquaculture and fishing industries”, Conference Proceedings/Papers OCEANS 2014, St. John’s, IEEE Xplore DOI:10.1109/OCEANS.2014.7002983

44. H. Plommer, I. Reim and F. M. Kerton*, “Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes”, Dalton Transactions, 2015, 44, 12098 – 12102. DOI: 10.1039/C5DT00220F OPEN ACCESS

**Cover Page**


B4. F. M. Kerton, “Chapter 17 – Ocean Resources for the Production of Renewable Chemicals and Materials” in “Chemical Processes for a Sustainable Future”, T. M. Letcher, J. L. Scott and D. A. Patterson (Editors), RSC Publishing, Cambridge, UK, December 2014. ISBN: 978-1-849739757

43. Y. Liu, C. N. Rowley* and F. M. Kerton*, “Combined experimental and computational studies on the physical and chemical properties of the renewable amide, 3-acetamido-5-acetylfuran”, ChemPhysChem, 2014, 15, 4087-4094, DOI: 10.1002/cphc.201402376

42. X. Chen, S.-L. Chew, F. M. Kerton and N. Yan*, “Direct Conversion of Chitin into a N-containing Furan Derivative”, Green Chem., 2014, 16, 2204-2212, DOI: 10.1039/C3GC42436G

41. Q. He,  J. W. O’Brien, K. A. Kitselman, L. E. Tompkins, G. C. T. Curtis and F. M. Kerton* , “Synthesis of Cyclic Carbonates from CO2 and Epoxides Using Ionic Liquids and Related Catalysts Including Choline Chloride-Metal Halide Mixtures”, Catal. Sci. Technol., 2014, 4, 1513-1528, DOI:10.1039/C3CY00998J. Invited Contribution for Themed Issue on “Catalytic Conversion and Use of Carbon Dioxide for Value-Added Organics

B3. F. M. Kerton and R. Marriot, “Alternative Solvents for Green Chemistry”, 2nd Edition, text book, RSC Green Chemistry Book Series, RSC Publishing, Cambridge, UK, (May 30, 2013).

Cover for 2nd Ed. of Alternative Solvents for Green Chemistry
Cover for 2nd Ed. of Alternative Solvents for Green Chemistry

40. J. N. Murphy, F. M. Kerton and L. N. Dawe*, “Single crystal structural characterization of trichlorotetrapyridylbismuth(III) and its pyridine solvate”, Journal of Chemical Crystallography, 2014, 44, 108-114, DOI:10.1007/s10870-014-0493-7

39. F. M. Kerton*, Y. Liu, K. W. Omari and K. Hawboldt, “Green chemistry and the ocean-based biorefinery”, Green Chemistry, 2013, 15, 860-871,DOI:10.1039/C3GC36994C, and inside cover art for this issue, and featured in Green Chemistry’s blog. One of the top ten most-accessed articles in Green Chem. in March 2013


38. N. Ikpo, J. C. Flogeras and F. M. Kerton*, “Aluminium coordination complexes in copolymerization reactions of carbon dioxide and epoxides”, Dalton Trans, 2013, 42, 8998-9006  DOI:10.1039/C3DT00049D

37. (Collaborative paper) S. C. Roşca, D. A. Roşca, V. Dorcet, C. M. Kozak, F. Kerton, J.-F. Carpentier* and Y. Sarazin*, “Alkali aminoether-phenolate complexes: Synthesis, structural characterization and evidences for an activated monomer ROP mechanism”, Dalton Trans, 2013, 42, 9361-9375 DOI:10.1039/C2DT32726K, 2013

36. N. Ikpo, S. Barbon, M. Drover, L. N. Dawe and F. M. Kerton*, “Aluminum methyl and chloro complexes bearing monoanionic aminephenolate ligands: synthesis, characterization and use in polymerizations”, Organometallics, 2012, 31,  8145-8158,

35. L. N. Saunders, M. E. Pratt, S. E. Hann, L. N. Dawe, A. Decken, F. M. Kerton and C. M. Kozak*, “Structural Variations in the Coordination Chemistry of Amine-bis(phenolate) Cobalt(II/III) Complexes”, Polyhedron, 2012, 46, 53-65.

34. K. W. Omari, L. Dodot and F. M. Kerton*, “A Simple One-Pot Dehydration Process to Convert N-acetyl-D-glucosamine into a Nitrogen-Containing Compound, 3-acetamido-5-acetylfuran”, ChemSusChem, 2012, 5, 1767-72, cssc.201200113.

33. N. Ikpo,  C. Hoffmann,L. N. Dawe and F. M. Kerton*, “Ring-opening polymerization of ε-caprolactone by lithium piperazinyl-aminephenolate complexes: Synthesis, characterization and kinetic studies”,  Dalton Trans., 2012, 6651 – 6660, DOI:10.1039/C2DT30276D

32. M. W. Drover, K. W. Omari, J. N. Murphy and F. M. Kerton*, “Formation of a renewable amide via direct conversion of N-acetyl-D-glucosamine”, RSC Adv., 2012, 2, 4642-4643,  DOI:10.1039/C2RA20578E

31. K. W. Omari, J. E. Besaw and F. M. Kerton*, “Hydrolysis of Chitosan Into Levulinic Acid and 5-Hydroxymethylfurfural In Water Under Microwave Irradiation”, Green Chemistry, 2012, 14, 1480-1487, DOI:10.1039/C2GC35048C. One of the top ten most-accessed articles in Green Chem. in April 2012.

30. Z. Hu, C. Schneider, C. Price, W. Pye, L. N. Dawe and F. M. Kerton*, “Coordination chemistry of α-ω-di(pyridyl-imine) ligands containing flexible linkers with copper(I)”, Eur. J. Inorg. Chem., 2012, 1773–1782, DOI: 10.1002/ejic.201101414

29. Z. Hu and F. M. Kerton*, “Simple copper/TEMPO catalyzed aerobic dehydrogenation of benzylic amines and anilines”,  Org. Biomol. Chem., 2012, 10, 1618-1624, DOI:10.1039/C2OB06670J

28. L. N. Saunders, N. Ikpo, C. F. Petten, U. K. Das, L. N. Dawe, C. M. Kozak* and F. M. Kerton*, “Coupling of Carbon Dioxide with Neat Propylene Oxide Catalyzed by Aminebisphenolato Cobalt(II)/(III) Complexes and Ionic Co-catalysts”, Catalysis Communications, 2012, 18, 165-7

27. Z. Hu and F. M. Kerton*, “Aqueous Room Temperature Aerobic Oxidation of Alcohols Using CuBr2 with TEMPO and A Polymer Based Pyridyl-Imine Ligand”,  Applied Catalysis A:General, 2012, 413-4, 332-339

26. H. A. Kalviri and F. M. Kerton*, “Dehydration of Benzyl Alcohols in Phosphonium Ionic Liquids: Synthesis of Ethers and Alkenes”, Advanced Synthesis & Catalysis, 2011, 353, 3178-3186

25. N. Ikpo, L. N. Saunders, J. L. Walsh, J. M. B. Smith, L. N. Dawe and F. M. Kerton*, “Zinc Complexes of Piperazinyl-aminephenolate Ligands”, European Journal of Inorganic Chemistry, 2011, 5347-5359. and cover art for last issue of 2011 (International Year of Chemistry).

Cover art for EJIC 2011
Cover art for EJIC 2011

24. H. A. Kalviri and F. M. Kerton*, “Synthesis of Pd Nanocrystals in Phosphonium Ionic Liquids Without Any External Reducing Agents”, Green Chem., 2011, 13, 681-686

23. A. V. Cherkasov, N. Ajellal, T. Roisnel, F. M. Kerton, J.-F. Carpentier* and A.  A. Trifonov*, “Neodymium borohydride complexes supported by diamino-bis(phenoxide) ligands: diversity of synthetic and structural chemistry, and catalytic activity in ring-opening polymerization of cyclic esters”,New. J. Chem., 2011, 35, 204-212 DOI: 10.1039/C0NJ00486C.

22. U. Kumar Das, J. Bobak, C. Fowler, S. E. Hann, C. F. Petten, L. N. Dawe, A. Decken, F. M. Kerton* and C. M. Kozak*, “Synthesis and Structure of Mono-, Bi- and Trimetallic Amine-bis(phenolate) Cobalt(II) complexes”,Dalton Trans, 2010, 39,  5462 – 5477.

21. S. M. Payne and F. M. Kerton*, “Solubility of Bio-sourced Feedstocks in ‘Green’ Solvents”,  Green Chem., 2010, 12, 1648 – 1653, DOI:10.1039/C0GC00205D..

20. H. A. Kalviri, C. F. Petten and F. M. Kerton*, “Catalytic dehydrative etherification and chlorination of benzyl alcohols in ionic liquids”, Chemical Communications, 2009, 5171-5173, DOI:10.1039/B909866F

B2. F. M. Kerton, “Alternative Solvents for Green Chemistry”, 217 page text book, RSC Green Chemistry Book Series, RSC Publishing, Cambridge, UK, (2009). ISBN: 978-0-85404-163-3

19. N. Ikpo, S. M. Butt, K. L. Collins and F. M. Kerton*“A Study of ligand coordination at lanthanide and group 4 metal centers by MALDI-TOF mass spectrometry”, Organometallics, 2009, 28, 837-842, om-2008-00453b

B1. F. M. Kerton, “Chapter 3 – Green Chemical Technologies” in “Introduction to Chemicals from Biomass”, J. H. Clark (Editor) and F. Deswarte (Co-Editor), J. Wiley & Sons Ltd, Chichester, UK, (2008). ISBN: 978-0-470-05805-3

18. K. L. Collins, L. J. Corbett, S. M. Butt, G. Madhurambal and F. M. Kerton*, “Synthesis of amine-phenol ligands in water – a simple demonstration of a hydrophobic effect” Green Chemistry Letters and Reviews, 2008, 1, 31-35, DOI: 10.1080/17518250701809030

17. F. M. Kerton*, S. Holloway, A. Power, R.G. Soper, K. Sheridan, J. M. Lynam, A. C. Whitwood and C. E. Willans, “Accelerated syntheses of amine-bis(phenol) ligands in polyethylene glycol or “on water” under microwave irradiation”, Can. J. Chem., 2008, 86, 435-443, DOI:10.1139/V08-043

16. C. E. Willans, M. A. Sinenkov, G. K. Fukin, K. Sheridan, J. M. Lynam, A. A. Trifonov* and F. M. Kerton*, “Lanthanide chloride complexes of amine-bis(phenolate) ligands and their reactivity in the ring-opening polymerization of e-caprolactone”, Dalton Transactions, 2008, 3592-3598, DOI: 10.1039/b802219d.pdf

17. J. H. Clark*, V. Budarin, F. E. I. Deswarte, J. J. E. Hardy*, F. M. Kerton*, A. J. Hunt, R. Luque, D. J. Macquarrie, K. Milkowski, A. Rodriguez, O. Samuel, S. J. Tavener, R. J. White and A. J. Wilson, “Green chemistry and the biorefinery: a partnership for a sustainable future”, Green Chem., 2006, 8, 853-860.

16. F. M. Kerton*, C. M. Kozak, K. Lüttgen, R. J. Webster, A. C. Whitwood and C. E. Willans, “Dimerisation versus polymerisation: Affects of donor position in isomeric dilithium diphenoxydiamine complexes”, Inorganica Chimica Acta, 2006, 359, 2819-2825.

15. F. M. Kerton*, T. Olsen, G. Grogan* and R. Marriot, “Biocatalytic synthesis of terpenoid esters in supercritical carbon dioxide”, Enzyme and Microbial Technology, 2006, 39, 621-625.

14. S. Saffarzadeh-Matin, F. M. Kerton*, J. M. Lynam and C. M. Rayner*, “Formation and catalytic activity of Pd nanoparticles on silica in supercritical CO2”, Green Chem., 2006, 8, 965-971.

Other publications pre-2006

ResearcherID: B-1444-2012


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